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We are scientists making technology useful to our customers and reducing an accident to an incident

Laboratory – Storage of chemicals

Storage of many different chemicals in a laboratory setting is done following a few simple rules

  • Store by chemical compatibility
  • Use secondary containment
  • Store the minimum quantity needed consistent with use requirements

The sorting of diverse chemicals found in laboratories by compatibility is often a difficult task. The safety data sheets may have some compatibility information, but this is frequently terse and difficult to interpret. The hazard classifications of the Global Harmonization System provides a starting point for setting up a storage compatibility program.

The following table lists the GHS-drived storage groups:

Storage groups according to GHS

Storage:
Group Sub-Division
Comment
Section 1
Explosives
Separate storage for 6 divisions of explosives
Explosive use and storage must follow rules of the local/national agencies have jurisdiction.
Compressed or liquified gases
Flammable gases
Non-flammable gases
Toxic gases
Oxidizer gases
Aerosols are stored with their corresponding GHS classification.
Flammable liquids
Local codes may apply
Flammable solids
Self-reactive chemicals
Pyrophoric liquids
Pyrophoric solids
Local codes may apply
Self-heating substances
May require refrigeration
Water reactive substances
Releases a flammable gas
Oxidizing liquids
All categories
Acids
Oxidizing solids
All categories
Bases
Organic peroxides
All categories
Corrosive to metals
Skin/eye corrosive
All categories
Acids
Bases
Section 2
Acute toxicity
All categories
Serious eye damage/irritation
All categories
Respiratory sensitivity
All categories
May require secure storage
Skin sensitizer
All categories
May require secure storage
Germ cell mutagenicity
All categories
Category 1 may require secure storage
Carcinogenicity
All categories
May be subject to local regulation
Reproductive toxic
All categories
Category 1 may require secure storage
Lactation effects
All categories
Specific target organ toxicity
Both single and repeated exposure, all categories
Category 1 may require secure storage
Aspiration hazard
Aquatic toxicity
Both acute and chronic

Chemicals in the storage groups in section 1 may require dedicated safety cabinets, dedicated rooms, or possibly outside storage, depending on quantities and local ordinances.

Chemicals in the storage groups in section 2 may be stored together, but placed in dedicated secondary containment within that location.

Secondary containment can be a simple polyethylene tray of sufficient size to contain 100 percent of the contents of the largest container in the tray. These trays can also be used within safety cabinets to provide further segregation, if needed.

The nest method to limit the amount of chemicals in a laboratory is “just-in-time” delivery. This arrangement with a supplier uses a scheme such as “order before 10am, deliver by 3pm”.

In the absence of a just-in-time program, then ordering chemicals in the smallest size containers consistent with needs must suffice. While this may increase the cost per container, it will reduce waste disposal costs and may also make more laboratory space available for work, rather than storage.

To learn more

About GHS
GHS regulations

Neal Langerman

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